APPLICATION OF TITANIUM OXIDE COATINGS FOR NEUTRALIZATION OF
HAZARDOUS CHEMICAL SUBSTANCES

О. Halak, N. Poltorak, О. Kravchuk, V. Synko, Y. Korol

ABSTRACT

Contamination of hazardous chemicals is currently considered one of the major environmental problems. The methods of purification of gaseous emissions depending on the physicochemical properties of pollutants, in particular dangerous chemical, their aggregate state, concentration in the gas environment are studied in this article. The effect of aerosol content such as dust and soot is analyzed as well as the efficiency of purification methods at different temperature intervals, methods of purification of multicomponent mixtures. The comparative characteristics of thermochemical, reagent, sorption and catalytic methods are given and the prospects of their application in filtering systems of stationary and mobile objects are evaluated. It has been proved that almost any organic compounds can be oxidized (mineralized) on the TiO2 surface. In practice, any photocatalytic air purifier includes a porous TiO2 deposited carrier, which is irradiated with ultraviolet rays and through which air is purged. Photocatalysis is suitable for domestic use as it can occur at room temperature. For example, a thermocatalytic method of destroying harmful substances requires preheating the air to a temperature above 200 ° C. Photocatalysis destroys substances that penetrate even through activated carbon filters. Features of formation of oxide coatings by plasma-electrolytic oxidation of titanium alloys are considered. It is proposed to refine the design of collective defense systems on armored vehicles and stationary facilities with additional installation in the filter-absorber of the grid with the deposited layer of catalytic material, which will neutralize various types of dangerous chemicals due to photocatalytic air purification.

KEYWORDS

Filtration system, collective protection system, hazardous chemicals, cleaning methods, titanium alloys, mesh, photocatalyst.

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REFERENCES

Kazmirchuk R., Larionov V., Ilchenko V. (2010). Sources and factors of occurrence of dangerous ecological situation in the area of ​​territorial defense. forces and means of detection and evaluation. Technogenic-ecological safety and civil protection. Vol. 1. P. 145–153.

Shabanova N., Sarkisov P., Sol-gel fundamentals of nanosized silica technology. M.: ICC “Akademknig”, 2004. 208 p.

Василиева М. (2018). FeOx, SiO2, TiO2 / Ti composites prepared using plasma electrolytic oxidation as photo-Fenton-like catalysts for phenol degradation. M.S. Василиева, В.С. Руднев, А.А. Zvereva, A.Yu. Ustinov, O.D. Арефива, В.Г. Kuryavyi, G.A. Зверев. Journal of Photochemistry and Photobiology A: Chemistry. 356. P. 38–45. https://doi.org/10.1016/j.jphotochem.2017.12.007

Karakurchi G., Sakhnenko M., After all M., Galak O., Menshov S., Matikin O. (2018). Oxide-metal catalytic systems for aluminum and titanium alloys for ecotechnology. 8th International Conference Science and Society. 9th November. Hamilton, Canada. Pp. 504–515.

Sakhnenko M. (2008). Modeling of the surface treat ment of passive metals. M.D. Сакхненко, О.В. Bohoyavlens'ka, T.O. Nenastina. Materials science. Vol. 44, N. 1. P. 79–86.

Galak O., Karakurkchi G., Gribinyuk Y. (2016). Ventilation installations (units) are stationary and armored. Weapons systems and military equipment. № 4 (48). P. 5–9.  https://doi.org/10.30748/zhups.2018.57.21

Galak A.V. (2018). Modern technologies for solving issues in the defense industry. A.V. Galak, N.D. Sakhnenko, I.A. Belousov, A.V. Kosarev, O.V. Linyvtsev. Збірник наукових праць ХНУПС, Харків. № 3(57). С. 138–143.

Zainishev A., Polunin G. (2012). The use of ultraviolet LEDs in photocatalytic air purifiers for air purification of cabins of mobile machines. Internet-magazine "Technosphere Security Technologies". Issue # 6 (46). (http://ipb.mos.ru/ttb).

 

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